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Special Report                                                                                                                                                                   Special Report


                          Table 4: Chemicals used in TFT                  fi cant  strides  in  reducing  its  environ-                                                                      Furthermore, the integration of
        Type                       Materials & chemicals                  mental impact by  decreasing the use                                                                           PV systems with advanced energy
        Basic materials            Gallium arsenide (GaAs),  cadmium tellu-  of toxic materials like  cadmium  and                                                                       storage technologies, like solid-state
                                                                                                                                                                                         batteries, is a key area of innovation
                                                                          lead, although challenges remain, par-
                                   ride (CdTe), copper-indium-gallium  selenite   ticularly  with regard to recycling and                                                                that  could  enhance  the  overall  effi -
                                   (CIGS), amorphous silicon.             disposal.                                                                                                      ciency and reliability of solar power
        Speciality gases           Argon,  fl uorine,  helium,  hydrogen  selenide,                                                                                                       systems.
                                   nitrogen trifl uoride.                     There has been progress in the
        Bulk gases                 Hydrogen, nitrogen, oxygen.            development of methods to recycle PV                                                                           CONCLUSION
        Silicon precursor gases    Dichlorosilane,  silane, silicon tetrachloride,   materials, especially silicon and metals                                                               The PV industry and the chemical
                                   trichlorosilane.                       used in contacts,  to reduce  waste and                                                                        industry are highly interconnected,
        Dopants                    Diborane, germane, phosphine, trimethyl   promote sustainability.                                                                                     with the latter playing a vital role
                                                                                                                                                                                         at multiple stages of the PV supply
                                   boron (all in hydrogen).               Durability and stability                                                                                       chain. The supply chain begins with
        Wet chemicals              Cadmium sulphide coating systems,  potas-  One  of  the  signifi cant  challenges                                                                      the extraction and processing of raw
                                   sium cyanide etching system.           with perovskite solar cells  has been                                                                          materials required for PV cell produc-
        Metallisation              Silver for grid and bus bar; solderable silver,   their  long-term  stability. But over the                                                           tion and goes all the way through to
                                   carbon electrode materials.            last decade, innovations in encapsula-          Fig. 5: Effi ciency comparison of technologies – Best lab cells vs. best lab modules.  installation, operations, maintenance
        Encapsulants               Polyvinyl butyral.                     tion, material engineering, and device     Source: Reference 2.                                                and eventually disposal at end-of-life.
                                                                                                                     materials like windows and facades, and  materials that could surpass current tech-  The chemical industry provides the
                             Table 5: Chinese PV manufacturing by component and province                             so contributing to the rise of applications.  nologies in effi ciency, cost, and sus-  foundational materials and processes
                                                                                                                                                       tainability, including quantum dots,  that enable the production, perfor-
        Province Rank in China  Polysilicon  Ingots          Wafers         Cells          Modules                      At the same time, the development  organic-inorganic hybrid materials,  mance,  and  sustainability  of  PV
        1                     Xinjiang       Inner Mongolia  Jiangsu        Jiangsu        Jiangsu                   of fl exible and lightweight PV panels,  and new perovskite compositions.  technology.
        2                     Inner Mongolia  Yunnan         Yunnan         Zhejiang       Zhejiang                  particularly with OPVs and TFTs, has
        3                     Jiangsu        Ningxia         Inner Mongolia  Sichuan       Anhui                     opened new possibilities for applica-  The  use  of  Artifi cial  Intelligence   The chemical industry has also been
        4                     Sichuan        Jiangsu         Jiangxi        Shaanxi        Hebei                     tions in wearables, portable chargers,  (AI) and Machine Learning (ML) in  key to driving the many innovations
                                                                                                                                                       optimising material properties and  that  have  led  to  signifi cant  improve-
                                                                                                                     and even space exploration.
        5                     Qinghai        Sichuan         Ningxia        Henan          Jiangxi                                                     manufacturing processes is expected  ments  in  effi ciency,  cost,  and  sustain-
        Chinese fraction of global  72%      98%             97%            81%            77%                       Future trends                     to drive  further innovations in  PV  ability. Over the last decade, advance-
        capacity                                                                                                        Research is ongoing into new  technology.                        ments in materials like perovskites and
        Top-5  Provinces fraction  93%       83%             81%            80%            84%                                                                                           innovations in manufacturing processes
        of Chinese capacity                                                                                                100                                                           have brought PV technology closer to
        Top-5  Provinces fraction  67%       81%             78%            65%            64%                                                                                           being a primary energy source world-
        of global capacity                                                                                                                                                               wide.
       Source: BloombergNEF 2021.                                                                                                  1980        1990                                         The future holds even more pro-
       This distributes the light evenly, which  traditional silicon cells in specific  architecture have significantly     10                                                           mise as new materials and technologies
       makes the CPV modules more effi cient.  applications.               improved their lifespan.                                                              2010                     continue to evolve, further integrating
                                                                                                                                                                                         PVs into our energy landscape, and
       Cost reduction                      The Experience Curve – also called   Advances in encapsulation  materi-      Module Price [infl  ation adujusted  2023 /Wp]  2000             further solidifying  the  bond  between
          Cost reductions have been driven  Learning Curve – shows that in the last  als and processes have also enhanced    1                                                           these the chemical and the PV indus-
       by innovations in material  synthesis  43 years module prices decreased by  the  weather  resistance  of solar mo-                                                                tries.
       and process improvements. For exam-  24.4% with each doubling of cumula-  dules, in general, extending their opera-
       ple, the cost of polysilicon production  tive global module production. Cost re-  tional  life under harsh environmental                                                          REFERENCES
       has decreased due to better production  duction results from economies of scale  conditions.                                                                  2020                1.  https://thundersaidenergy.com/
       technologies and economies of scale.  and technological improvements.                                                0.1                                                             downloads/global-polysilicon-pro-
                                                                          Integration and applications                       0.001    0.01    0.1    1      10     100    1000    10000     duction-capacity/
          The commercial viability of  TFTs  Sustainability and environmental   There has been substantial progress                           Cumulative Production [GWp]                2.  Photovoltaics Report, Fraunhofer
       like Cd-Te and CIGS has also im-  impact                           in Building-Integrated PVs (BIPVs), i.e.,                         Fig. 6: Price Learning Curve.                   Institute for Solar Energy Systems,
       proved, making them competitive with   The PVs industry has made signi-  integrating solar cells into building   Includes all Commercially available PV Technologies [Reference 2].  29 July 2024.


       184                                                                   Chemical Weekly  October 22, 2024       Chemical Weekly  October 22, 2024                                                               185


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