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Special Report                                                                   Special Report



 Photoelectrochemical water splitting – a promising   concept can be seen in the Figure taken   Among all these, it has been reported  4.  Hydrogen production by photo-
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       from the lab’s literature  available in  that the combination of semiconduc-
                                                                              electrochemical water splitting,
 technique for hydrogen production  public domain.  tors and heterogeneous co-catalysts  is   US Dept. of Energy, https://www.

                                                                              energy.gov.fuelcells.
                                         one of the most effective  approaches
                                                                 IndiaChemTrade
                    ChemImpex
          While  Fujishima and Honda used  to improve PEC performance for solar  5.  I.R. Hamdani,  A.N. Bhaskarwar,
 nvironmental  degradation  and  taic panels) as electrode systems or as   A.K. DAS  TiO  as the  photocatalytic  material,  fuel production.   Free for subscribers of Chemical Weekly
                      For subscribers only
                                                                              Recent progress in material selection
          2
 climate change  due to carbon  slurry-based particle system, each with   Retd. Industrial Adviser  since then many materials like gallium   and device for PEC water splitting,
       ChemImpex, the trade database, tracks, on a daily
                                                         IndiaChemTrade provides consolidated trade statistics
 Eemissions  from  burning  fossil  its own advantages  and challenges.   Department of Chemicals & Petro-  nitride, silicon, tungsten oxide, bismuth  Concluding remarks  Renewable & Sustainable Energy
                                                         of India. The information provided here is based on the
       basis, exports and imports of chemicals and related
 fuels has triggered the need for sus-  To date, panel  systems  have  been the   chemicals, Government of India  vanadate, etc. have been studied by   PEC water splitting is a promising   Reviews, Vol. 138, March 2021.
       products through the major ports in India — a vital
                                                         annual trade data published by the Directorate General
 tainable and renewable energy source.  most widely studied owing to similari-  Email: amiyakantidas2010@gmail.com  different researchers.  technique  for producing H  and O .
                                                                       2
                                                                2
 Hydrogen, especially green hydrogen,  ties with established photovoltaic panel   source of commercial intelligence. Find out on-line   of Commercial Intelligence and Statistics, Government
                                                                                ABOUT THE AUTHOR
                                         However, many challenges and limita-

 is seen as having the potential to meet  technologies.  The  process has  been  National  Renewal Energy Laboratory,   how international markets are moving; where your   of India. The database can be searched by: Chemical
          Various  theoretical models  have  tions are yet to be overcome. With lite-
                                                                              Mr. Amiya  Kanti
 global  energy  requirement.  It  is an  demonstrated in  a  laboratory scale in  USA.  Both panel and slurry reactor   been used to study the interfacial  rature  fl ooded  with  new  reports,  it  is  Code to obtain the consolidated
       competitors are exporting and at what price; where
                                                         Name/Harmonised
 energy source as well as energy carrier.   behaviour of the electrode and electrolyte  hoped that a tangible process-technology   Das (born 1939) is
                                                         trade (import or export) in that item; or by Country to
       imports are coming from and how their prices are
 Moreover, it is also clean burning,   function, and to determine the optimal  for PEC water splitting will emerge   a B.Sc (Hons.) and
                                                         obtain the trade (import or export) in all chemicals and
       moving. Download all this data, seamlessly, for a
                                                                            M.Sc  in Chemistry
 evolving only water on combustion.  reactor design; aid material develop-  in near future.  related products between India and that country
       small fee — online, anytime, with no hassles.
       ment; and to understand the free ener-                               from  Calcutta Uni-
 Photoelectrochemical  (PEC) water   gies of solid-liquid interfaces.  Further reading  versity. Widely travel-
                                          ChemXchange
 splitting is  a  method that generates   1.  Photoelectrochemical water  split-  led in Europe and
                                Open to all registered users — no subscription required
 hydrogen from water using solar radia-  To improve the PEC performance,   ting an ideal technology for pure   India, he was a regular contributor
       ChemXchange — the chemical exchange with a difference — is where you can identify your buyers and sup-
 tion. In PEC water splitting hydrogen is   efforts are ongoing including  various   hydrogen, Nitu Singh Parihar et al,   in chemical journals during 80’s
       plyers on-line, any time. This unique platform is free to all advertisers in the print version of Chemical Weekly.
 produced from water using sunlight and   strategies such as:  J. Chem Soc., Vol. 97, July 2020,   and 90’s and is profi cient in German
 specialised semiconductors, called photo-      Bandgap engineering by developing   1099-1103.  and Russian. Before superannua-
                       For more information contact: 022-24044477. Fax: 022-24044450
 electrochemical materials, which use   narrow bandgap semiconductors that  2.  Roel K., Photoelectrochemical   tion on May 31, 1997 from the post
                  Email: corporate@chemicalweekly.com or log on to chemicalweekly.com
 light energy directly to dissociate a   absorb light over a wide range of   Hydrogen Production, 1st Ed, 2012,   of Industrial Advisor in the Dept. of
 water molecule into H  and O . In 1971,   wavelength;   Springer Science & Business Media.  Chemicals and Petrochemicals,  he
 2
 2
 Fujishima and Honda fi rst successfully       Incorporating metal nanoparticles;   3.  The Principles of PEC Water Split-  dealt with  diverse  chemical indus-
 demonstrated that TiO   could be used       Developing co-catalysts etc.  ting, World Scentifi c Publishing.  tries for three decades.
 2
 to decompose water to H  and O . (A.
 2
 2
 Fujishima  & K Honda, Nature, 1972,
 238, 37). Since then, considerable
 efforts have been made towards the com-
 mercial feasibility of this research area.
 PEC water splitting process              Missed a copy !!!
 The PEC water splitting  process
 uses semiconductor  materials  to con-
 vert solar energy directly  to chemical   For Digital Edition of this month’s issue & all other past issues
 energy in the form of H . The semicon-
 2
 ductor  materials used in  PEC process
 are similar to those used in photovoltaic   Visit www.hpicindia.com
 solar electricity generation. But for
 PEC applications the semiconductor is             Mrs. Usha S. - usha@hpicindia.com
 immersed in a water-based electrolyte,   PDF copies available for download
 where sunlight energises the water-
 splitting process. Water splitting reac-   Register Now
 tion occurs both in acid electrolyte
 as well as basic electrolyte.  Contact: For Subscription  : Mrs. Usha S. - usha@hpicindia.com
                                 For Advertising  : Mr. Vijay Raghavan - vijay@hpicindia.com
 The PEC reactors can be constructed
 in panel form (similar to photovol-
 170  Chemical Weekly  July 30, 2024  Chemical Weekly  July 30, 2024                                   171
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