Page 174 - CW E-Magazine (13-2-2024)
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Special Report                                                                                           For your requirements of:
                                                                                                                       D-(-)-Tartaric Acid w L-(+)-Tartaric Acid
                                                                                                                               DL Tartaric Acid
       binding sites is reported and has the size  Zwitterionic “Solutions” for  Process design and optimisation       Disodium Octaborate Tetrahydrate
       of C H  molecule, which can allow more   reversible CO  capture    of enzymatic reaction distilla-                         (Boron 20%)
            6
          2
       accessible channel surfaces for C H . For       2                  tion (RD)                                             Zinc Borate
                                  6
                                2
       50/50 mixture, selectivity of 2.82 and   G.L.P. Aydos et al have worked on the  [This column has covered many papers on   Boric Acid (Boron 17%)
       C H  uptake of 53.8  cc per gm at 25°C   Zwitterions resulting from the covalent  RD where the exothermicity of the reac-  Boric Oxide w Boron Oxide
        2
          6
       and 1 bar is reported. DFT calculations   attachment of 3- or 4-hydroxybenzene  tion is gainfully employed and large scale   Borax Anhydrous
       were done. (Sepn. Purfn. Technol., 2023,   to the 1,3-dimethylimidazolium cation,  adoption has been reported eg MTBE]  Borax Pentahydrate (Boron 15%)
       323, 15 Oct., 124465; DOI:10.1016/j.  which have pKa of 8.68 and 8.99 in                                         Borax Decahydrate (Boron 10.5%)
       seppur.2023.124465).              aqueous solutions, respectively. This   J. Liang et al have worked on the high            Contact :
                                                                          efficiency of enzymatic reaction and             Satyanarain & Co. /
       Tailoring chemical absorp-                                         distillation separation to get over the         LCG Eximchem Pvt Ltd
       tion-precipitation to lower the                                    limiting effects of reaction equilibrium;   21-22 Abhishek, 303, Samuel Street, Vadgadi, Mumbai - 400 003.
       regeneration energy of a CO                                        product inhibition and the difficulty of      Phone: +91- 22 - 23437035 / 23423229 / 49744840
                                                                                                                            Cell: +91- 9820496607 / 9930817512
       capture plant                 2                                    product recovery. The lipase CALB was        Email: satyainfo.gupta@gmail.com/info@lcgexim.com/
                                                                                                                               lcgeximchem@gmail.com
       [This column has covered many papers                               immobilized and coated on the θ-ring
                                                                          by sol-gel method. The test reactor was
       on this topic as CO  removal, with mini-                           synthesis of n-butyl acetate by trans-            AVAILABLE
                      2
       mal energy consumption in regeneration,                            esterification. Their work shows long                  IODINE
       has become important in the context of                             term stability of immobilized enzyme and    Calcium Iodate  Iodine Trichloride
       climate change.]                                                                                               Copper Iodide  Periodic Acid Solution
                                                                          upto 120 days was tested. [Sepn.Purfn.      Ethyl Iodide  Potassium Iodate
                                                                          Technology, 2023, 327, 15 Dec, 12488;       Hydroiodic Acid
       G.G. Jang  et al have investigated                                 DOI:10.1016/j.seppur.2023.124888].          Iodic acid Solution  Potassium Iodide
       CO  fixation in a solid form through                                                                           Iodine        Povidone Iodine
                                                                                                                                    Sodium Iodide
          2
       solvation followed by ionic self-                                  Separation of volatile organic              Methyl Iodide  Sodium Metaperiodate
       assembly-aided precipitation without   solution chemisorbs CO  in aqueous   compounds (VOCs) from              Tri Methyl Sulfoxonium Iodide
                                                             2
       requiring high energy for solvent re-  solutions 0.58 mole per mole of CO    viscous liquids with Rotating              SELENIUM
                                                                       2
                                         at 1.2 bar (absolute) and 40°C. Further,                                     Selenium Dioxide  Sodium Selenate
                                         equimolar amount of chemisorbed CO    Packed Bed (RPB) technology            Selenium Metal  Selenium Sulfide
                                                                       2
                                         in these solution are found at 10 bar   J. Koop et al have worked on the title   Sodium Selenite
                                                                                                                            Manufacturers & Supplier By
                                         and 40°C. Bicarbonate ions are formed   problem which is frequently encountered   RITESH CHEMICAL INDUSTRIES PVT LTD
                                         in the aqueous solution and energy is   in industry as invariably there is require-  B1/304,2nd Floor, Laram Centre, M.A Road,
                                         lower than MDEA solution. The solution   ment of very low content of VOC’s. The   Near Andheri Railway Station, Andheri (West),
                                                                                                                           Mumbai – 400058, Maharashtra, INDIA.
                                         was recycled 20 times. (ChemSusChem;   system considered was polysiloxane    Phone: 8767854756, 9920868483, 9867260490
                                         DOI: 10.1002/cssc.202300971).                                                Email: riteshchemicalindustriespvtltd@gmail.com
                                                                                                                      Website: www.riteshchemicalsindustries.com
                                         Adsorption and desorption
                                         behaviours of NH  on zeolites                                                  Available Regularly for LOCAL / EXPORTS                                     Available
                                                           3
                                         at 200°C by the pressure-swing                                                           2,4-DI CHLORO PHENOL                                     FORMALIN TOLUENE ACETIC ACID
                                                                                                                                                                                           BUTANOL BENZENE
                                                                                                                                                                                                                THF
                                         method                                                                                 2,4,6-TRI CHLORO PHENOL                                   GLYCERINE XYLENE    ACETONE
                                         M. Tokushige and J. Ryu have studied  which was subjected to the low mol.                2,6-DI CHLORO PHENOL                                     SORBITOL   MIBK     HEXANE
       generation. Thus monovalent Na  was  various zeolites – Y, A, L and mordenite –   wt. cyclic siloxane components and the   PARA CHLORO PHENOL                                         Contact: MONISH CHEMICALS
                                  +
       introduced into an aqueous solution  and the effect of their pore sizes,   VOC xylene at 140°C. The pressure                                                                           Email: monishchemicals@yahoo.com  (2)
       of 1,6-hexanediamine. This strategy  countercation species, and the number  in the RPB was in the range of 5-20           ORTHO CHLORO PHENOL                                           Mobile: 9323040835 / 8850079682
       results in energy consumption of 3.4  of adsorption sites on the adsorb of   mbar and rotational speed from 300-                  PARA ANISIDINE
       GJ/tonne CO , which is lower than  NH . It is useful to find that despite repe-  1500 rpm. In addition counter currently        ORTHO ANISIDINE                                         Manufacturers & Exporters of
                                                                                                                                                                                                Iso Amyl Alcohol
                  2
                                           3
       the state-of-the art polyethyleneimine,  titive lattice expansion and shrinkage  flowing stripping gas was used and this                                                                  n-Amyl Alcohol
       CaCO  and bis-iminoguanidines sys-  that the morphologies of the zeolite  resulted in further lowering of VOC’s.                      Contact Manufacturers:                         (1-Pentanol / n-Pentanol) Purity >99%
            3
                                                                                                                                                                                                     Mix Butanol
       tems; which require 3.5-10.2 GJ/tonne  particles were not degraded. This work  This study shows that RPB can be an                         109, ‘Udyog Kshetra’, 1st Floor,        •  Specifications & Quality as per International Standards
       CO . Molecular dynamic simulation  shows the utility of using zeolites. (ACS  effective way for the title objective. [Ind.                 Mulund - Goregaon Link Road, Off. L.B.S. Marg,    •  Export Inquiries Solicited
          2
       were done. (ChemSusChem;  DOI:  Omega, 2023; DOI: 10.1021/acsome-  Eng.Chem.Res., 2023, DOI:10.1021/acs.                                   Mulund (West), Mumbai 400 080.          Please Contact: Yashvardhan Industries
       10.1002/cssc.202300735).          ga.3C02882).                     iecr.3C01597].                                                          Tel.: +91-22-67976640, 67976657             49 C, Maxi Road Indl. Area, Ujjain - 10. MP.
                                                                                                                                                  Email: info@valiantorganics.com                (M): 09301811009, 09425093006
                                                                                                                                                                                          (E): yash@yashvindustries.in w (W): www.yashvindustries.in
                                                                                                                     13/29
       174                                                                  Chemical Weekly  February 13, 2024
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