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Special Report


                                                                          and this was confirmed by SEM, EDS
                                                                          and XPS. With the removal of PVDF,
                                                                          leaching can reach 93.25% and 93.3%
                                                                          for Li and Co, respectively. (Sepn. Purfn.
                                                                          Technol., 2023, 324,1  Nov., 1246011;
                                                                                            st
                                                                          DOI:10.1016/j.seppur.2023.124601).

                                                                          High-efficiency leaching of Li
                                                                          and Ni from spent Li-ion batte-
                                                                          ries based on sodium persulfate

                                                                          Q. Hu et al have reported preferential
       distribution factor, and mass transfer  These aspects need to be considered in   leaching of Li and Ni from spent batte-
       coefficient  are  considered. The first  greater details. Deformebility of com-  ries via first reduction roasting to destroy
       proposal refers to the optimisation of the  ponents: Particles/components in a food   the stable structure of cathode, and then
       operating curve, divided into cooling pro-  product are usually flexible in their shape   leaching with Na S O  was done and in
                                                                                            4
                                                                                        2 2
       cess regulation and temperature-cycling  and size and they can swell or deswell.   the solution Li  and Ni  ion exist while
                                                                                      +
                                                                                            2+
       strategy. These can eliminate fine crystals.
       The role of the stirring intensification is   Cascaded membrane use is discussed. It
       considered. The coupling technique that   is possible to get many different starting
       combines suspension and LMC has been   materials from different feeds such as
       designed. The crystal seeds generated   milk, amongst others, for food produc-
       above can flow into the tubular crystal-  tion. This has been considered for whey
       lizer and act as sites for crystal growth.   protein and oligosaccharides. Reducing
       An example of isophthaloyl chloride is   energy consumption for removing
       reported. (Sepn. Purfn. Technol., 2023,   bacteria can be possible using a membrane  Co and Mn remained in the residue in the
       324, 1  Nov., 124428; DOI:10.1016/  process. Details of skim milk are given.  form of Co O and MnO . The leaching
            st
                                                                                   3
                                                                                     4
                                                                                              2
       jspepur.2023.124428).             There is an innovative opportunity, e.g.,   efficiency of Li and Ni were 95% and
                                                                          96%, respectively. The mechanism of
       Rethinking membrane processes     the use of waste stream, in this case    leaching  was  tracked  through  XPS,
       (MPs) for food                    delactosed whey from a dairy plant.   XRD and SEM-EDS. (Sepn. Purfn.
                                         A lot more is to be gained in this area,   Technol., 2023, 325, 15 Nov., 124653;
       K. Schroen and I.B. deAugujar have given   e.g., design of membranes. (Chemie. Ing.   DOI: 10.1016/j.sep.pur.2023.124653).
       a very useful comprehensive account   Tecknik; DOI: 10.1002/cite. 202300070).
       of this subject of considerable practical                          Optimal tunnel dryer operating
       relevance. The key advantage of MPs is   Lithium (Li) and Cobalt  strategies for the production of
       relatively low energy consumption and   (Co)                       ceramic roof tiles under tight
       it allows fractionation of various feeds
       (e.g., milk) into starting materials for                           quality consideration
       food design. There is a scope for further   Sustainable approach for leach-
       considerable progress in this area. The   ing of Li and Co in spent Li-ion   A.L. Arvanitidis et al have worked on
       specific properties of the components of  batteries without liberation by   an existing industrial-scale tunnel and
       interest need to be taken into account,  overall pyrolysis         the primary focus of the study was to
       such as deformability in relation to the  [In view of looming shortage of Li, Co,   control  the  shrinkage  stage,  during
       actual membrane structure. There is scope  etc. it has become necessary to give   which product fracture risk is highest,
       to adopt cascade system. The use of high  impetus to recover these valuable metals   with the minimum energy cost possible.
       turbulence to intensify mass transfer is  from used batteries; this column has   This study first gave 1.5% fuel economy.
       discussed.                        covered some papers.]            The dryer productivity was increased by
                                                                          9.5%. The case of two different raw clay-
       Many aspects are discussed: Particle  Si-qi Jiang et al have pyrolysed undisso-  based ceramics was considered. (Ind.
       behaviour in flow; molecular diffusion;  ciated electrode sheets at 480°C, which  Eng. Chem. Res., 2023; DOI: 10.1021/
       sheer-induced diffusion; internal lift.  removed in an effective way PVDF  acs.iecr.3C01514).


       Chemical Weekly  February 13, 2024                                                              171


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