Page 175 - CW E-Magazine (12-3-2024)
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Special Report


       panies) enterprise, which is represented  International  Business Machines Cor-  uids  including oils, diesel, naphtha,
       by Shuye  Environmental  Technology  poration  (IBM) (Armonk, NY, USA),  and monomers as well as syngas, char,
       (Shantou, China).                 DuPont  Teijin  Films (Tokyo, Japan),  to waxes. Depending on the obtained
                                         and Dow (Midland, MI, USA).      products these can be utilised as renew-
       Enzymolysis                                                        able feedstocks for the production of
          An  alternative path represents   Pyrolysis                     new polymers.
       enzymolysis, a technology based on bio-  With  pyrolysis, a thermochemical
       chemical  processes  utilising different  recycling process  is  available that   With 40,000-tpa, the second-largest
       kinds of biocatalysts to depolymerise a  converts or depolymerises mixed   capacity found in the report is realised
       polymer into its building units. Being in  plastic wastes (mainly polyolefins) and  with pyrolysis. The majority of the 80
       an early development phase, this tech-  biomass into liquids, solids, and gases   identified  technology  providers  are
       nology is available  only at  lab-scale.  in presence of  heat and  absence of   located in Europe (42 providers) followed
       Currently, only one enzymolysis tech-  oxygen. Obtained products range from  by North America (21 providers), Rest
       nology provider was identified, which  for  instance different fractions of  liq-  of the world (11 providers), China (four
       is a small enterprise located in Europe.

       Solvolysis
          The solvent-based solvolysis
       describes a chemical process based on
       depolymerisation, which can be realised
       with  different  solvents.  This  process
       breaks down polymers (mainly PET)
       into their building units (e.g. mono-
       mers, dimers, oligomers). After break-
       down, the  building  units  need to  be
       cleaned from the other plastic compo-
       nents (e.g. additives, pigments, fillers,
       non-targeted polymers).  After cleaning,
       the  building units  are  polymerised to
       synthesise new polymers.

          With 24 companies, fewer solvo-         Fig. 2: Installed and running advanced recycling plants in EU27+3.
       lysis technology providers are  on the
       market  compared to pyrolysis, also
       offering smaller capacities  typically
       between 550-8,7500 tpa. Of  the iden-
       tified  solvolysis  technology  providers
       a majority  are located  in Europe (14
       providers) followed by North America
       (seven providers), Japan (two provi-
       ders, and China (one  provider).  With
       nine companies  the majority of  pro-
       viders are mainly small  enterprises
       followed by large- (seven companies),
       medium- (five companies), and micro/
       start-up (two companies) enterprises.
       Among the large enterprises, there are
       Aquafil  (Arco,  Trentino,  Italy,  East-
       man Chemical  Company (Kingsport,
       TN, USA),  IFP Energies Nouvelles
       (IFPEN)  (Rueil-Malmaison, France),   Fig. 3: Installed input capacities for different advanced recycling technologies in EU27+3.


       Chemical Weekly  March 12, 2024                                                                 175


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