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News from Abroad                                                              News from Abroad


 COLLABORATION                                                            Trevi Systems have successfully deve-
 Nippon Shokubai’s materials help US fi rm demonstrate                     loped a draw solution with the capabi-
                                                                          lity of improving water production by
 feasibility of forward osmosis technology in seawater                    30% compared with the previous pro-
                                                                          duct.  The FO system is under considera-
 desalination                                                             tion  to  be  introduced  for  seawater
                                                                          desalination  in  areas  with  high  demand
                                                                          for  water,  such  as  the  Middle  East,
 Japanese  chemicals  fi rm,  Nippon                                       as  well  as  for  brine  concentration  to
 Shokubai,  has  combined  forces  with                                   achieve  zero  liquid  discharge.  Nippon
 US-based  Trevi  Systems  in  the  deve-                                 Shokubai  said  it  will  make  further
 lopment of the draw solution as a key                                    efforts  to  improve  the  performance  and
 component in the forward osmosis (FO)                                    functions of the draw solution with a view
 system, which is a next generation system   Fig. 2                       toward future expansion of the FO system.
 for seawater desalination and water treat-  LIFE CYCLE ASSESSMENT
 ment. Trevi Systems recently celebrated
 the successful completion and operation   ‘Products made from crude oil have a signifi cantly
 of  its  500m /day  renewable  seawater
 3
 desalination plant at the Natural Energy   higher CO  footprint than previously assumed’
 Laboratory of Hawaii (NELHA) site in   Fig. 1  2
 Hawaii, US. This project, made possible    For years, the life cycle assessment
 by  a  $4-mn  US  Department  of  Energy   (LCA) community has been discussing
 grant awarded to NELHA in 2022 with   how to make a fair comparison between
 Trevi  as  the  technology  provider,  is   products made from crude oil and those
 being seen as an important development   made from biomass, from Carbon Cap-
 in renewable desalination.  ture  and  Utilisation  (CCU)  and  from
       recycling. A regularly critically empha-
 The initiative, aimed at demonstrat-  sised  aspect  is  that  while  all  possible
 ing  the  feasibility  and  effi cacy  of  for-  Photo 1  environmental impacts of – often novel –
 ward  osmosis  technology  in  seawater   The  FO  system  is  focused  on  as  a  vered  water  using  low  grade  thermal   renewable  carbon-based  products  are
 desalination  for  agricultural  applica-  means that will resolve this issue. The  heat (see Photo 1).  analysed  at  great  expense  and  inclu-
 tions, surpassed expectations during its  FO  system  utilises  the  osmosis,  which   ded in the LCA, for crude oil the scru-
 operation from June 2022 to September  is  a  natural  process  and  occurs  when   The key elements of Trevi Systems’   tiny appears to be less stringent. Here,
 2023. By harnessing solar power, Trevi’s  liquids  of  differing  solute  concentra-  FO  system  are  the  use  of  retrograde   standard values are frequently applied
 forward  osmosis  system  accomplished  tions  are  separated  by  a  semi-permea-  thermolytic  solute  draw  solution  and   that  do  not  fully  account  for  regional
 a  fi rst  in  renewable  desalination,  pro-  ble membrane and water moves by the  recycling  of  the  draw  solute  back  to   differences, lack granularity and trans-
 ducing  potable  water  without  reliance  process  of  osmosis  from  the  solution  the  FO  membrane  (see  Figure  2). Trevi   parency, and do not take into account   Source: nova-Institute GmbH
 on an external energy grid for support.  of lower concentration to that of higher  Systems conducted a pilot test to demon-  a  number  of  impacts  on  similar  level  Empa, Agroscope, and the Paul Scherrer  vant database in Sphera (GaBi) is also
 Reverse  osmosis  (RO)  is  widely  used  concentration. In the seawater desalina-  strate the production of fresh water at a   of  detail  than  what  is  requested  for  Institute,  with  the  aim  to  create  a  working on updating their data accord-
 in  the  seawater  desalination  for  agri-  tion, the FO system utilizes the differ-  volume of 50 m  per day from seawater   non-fossil alternatives.  comprehensive,  consistent,  and  trans-  ingly, as per nova-Institute.
 3
 cultural and drinking water use and for  ence  in  solute  concentration  in  sea-  in  the  UAE  in  2016,  which  confi rmed   parent Life Cycle Inventory (LCI) data-
 treatment  of  industrial  water.  The  RO  water and draw solution, and the natural  that  the  use  of  the  FO  system  was  able   According  to  German  research  base for environmental assessment.  The  ecoinvent  v3.9  introduces  an
 system is a technology that involves the  osmotic pressure as a result of the draw  to  reduce  electric  power  consumption   institute,  nova-Institute  GmbH,  new   extensive overhaul of the data on natu-
 pressurisation of seawater or wastewater  solution on one side of a FO membrane  to about 1/3 compared to that of the RO   data  sets  from  the  Swiss  ‘ecoinvent’   The two latest updates (3.9 and 3.10  ral gas and crude petroleum oil supply,
 over an RO membrane to remove salts  (a  semi-permeable  membrane)  to  pull/  system.  However,  the  improvement  in   database have substantial implications  of end-2023 versions) of the ecoinvent  while in the 3.10 update, the chemicals
 (such  as  NaCl)  and  impurities.  While  transport fresh water from seawater into  the amount of water production is nece-  for  the  comparison  of  renewable  car-  database, which is the basis for many  sector  is  updated  to  improve  the  data
 this  system  enables  the  acquisition  of  the  draw  solution  with  everything  tak-  ssary for the widespread utilisation of   bon-based  and  fossil  crude  oil-based  European LCAs, have new data on the  representation  for  essential  chemical
 high-quality water, the large amount of  ing place under low pressure and energy  the  FO  system  at  full  scale,  and  the   plastics.  supply of crude oil and natural gas, and  precursors  and  their  derivatives,  such
 electric power consumed by the pressu-  conditions (Figure 1). Nippon Shokubai  improvement in the function of the draw   for  the  fi rst  time  include  unintended  as  short-chain  alkenes  (ethylene,  pro-
 rising pump is considered an issue (see  and Trevi Systems developed the draw  solution as the key component is crucial   ecoinvent  was  founded  by  the  methane  emissions  during  extraction  pylene, butene, and butadiene), mono-
 Figure 1).  solution to be separated from the reco-  for realising this. Nippon Shokubai and   Swiss research institutions ETH, EPFL,  and  processing.  Another  highly  rele-  cyclic aromatics (benzene, toluene, and


 158  Chemical Weekly  March 12, 2024  Chemical Weekly  March 12, 2024                                 159


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