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Special Report                                                                                         Consignment Agent of Organic Ind. Ltd.          Your Total Chemical Solutions Partner
                                                                                                                              BORIC ACID
                                                                                                                         Technical / Pure / Granular / Powder  Zhejiang Haute / Zhejiang Fenghong  Rheology Modifier Bentonite Clay.
                                                                                                                          Borax Decahydrate Granular / Crystal  PT. Darisa Intimitra   Matting Agents - Treated & Non-Treated for Wood Coatings /
       Gold-free catalysts for                                                                                          Borax Penta Hydrate l D.O.T. (Boron 20)                Can & Coil Coatings. Antiblocking Agent for Printing Inks
       production of vinyl acetate                                                                                          Potassium Permanganate      CVC Thermoset Specialties   Specialty Modified Epoxy Resin, Functional Reactive Diluents, Liquid
       (VA)                                                                                                                (FFG / Technical / Crystal / Granular)  (Huntsman)   Reactive Polymers - Toughner, Latent Curing Agents.
       [The Wacker process, in vapour phase,                                                                             Potassium Persulphate / Hexamine                      Epoxy Curing Agent - Polyamine, Aliphatic & Cyclo- Aliphatic Adducts
       for C H + O + CH COOH to VA was                                                                                   Potassium Carbonate Granular / Powder  Karntner Montain Indusrie -KMI   Micaceous Iron Oxide - MIOX®
           2
                       3
                 2
             4
       a breakthrough process, which used Pd                                                                             Polyelectrolytes Flocculating Agent  Van Barele       Silicate Binder for Paint & Plaster, Silicate Binder for Zinc
       and Au based heterogeneous catalyst.]                                                                               Water Treatment & ETP Plant                         Anticorrosion Coatings, Concrete Hardner.
                                                                                                                         Trichloroisocyunaric Acid (TCCA 90)
       There is a report in Chem. Eng. Prog.,                                                                          Calcium Hypochlorite 65% / 70%  l SDIC  Denka           Construction Chemicals, Styrene and Acetyl Products, Elastomers.
                                                                                                                                  Contact:
       A.I.Ch.E., in collaboration with US NSF                                                                          MANALI TRADERS                  Megasil - Silanes      GLYMO, MONO AMINO, DI AMINO, AMEO, VTMO, MEMO, DAMO.
       to come out with catalyst free from gold.                                                                              Mumbai - 400 009.         AECI                   Asphalt Emulsifier and Adhesive
       VA has a market value of $10 billion per                                                                            Tel.: 022-66312532 / 49765200  Jiangsu Ruijia       Solvents (Food Grade)
                                                                                                                          Mob.: 09223432532 / 9970602532
       annum, and a production of 10-mtpa.                                                                               Email: manali_traders@yahoo.co.in  Kuraray            Solvents
       and this demand is increasing also due  exposed active sites and special elec-  Hydrogenation process                 sales@manalitraders.in
       to rising solar energy adoption where  tronic structure. TD materials have more   intensification of 2-nitro-4-                                  Dezhou Huiyang         Food Texturing, Prolong Shelf Life of Food
       VA-based polymers offer a way to encap-  well-defined structures compared to real   acetylamino anisole (NAAA)                                   Lianyungang Tongyuan   Acetate, Propionates, Formates for Food Grade
       sulate and protect the solar cells.  The   catalysts, which are usually bulk or parti-   by HiGee technology      emulsifier                     Aekyung                Plasticizer, Synthetic Resins.
       vapor phase reaction is carried out at  cle.  TD can be helpful for the precise                                NP / OP Ethoxylates * SP Ethoxylates  Siltech            Silicons Surfactants
       160-180°C and 6-8 atm. Both Pd and Au  design of catalyst. Transition metal dichal-  2-Amino-4-acetylaminoanisole (AMA),   Stearic / Oleic / CFA Ethoxylates  Radco     Thermal Fluids
       are expensive ($2,000 per oz) and there  cogenides, metal and metal (hydr)oxide  obtained  from  NAAA,  is  a  crucial  in-
       is leakage of gold during catalyst pro-  materials are referred. TD materials serve  termediate in the production of disperse   CSA / TDA / OCA / LA Ethoxylates  Dow   Dowsil Releasing Agents
       duction. Metal leaching happens during  as models to explore the structure-active  dyes, such as Disperse Blue 79/291 and   Tallow / Oleyl / Coco / Stearyl Amine Ethoxylate  Argenol Laboratories   Gold, Silver, Platinum based Ingredients & Antimicrobial Agents
       production and catalyst replacement  relationship by combining theoretical cal-  Disperse Purple 58. X. Zhang et al have   Acid Thickener for HCl  Soken Tecnix         Thermal Fluids
       happens in one to two years. P. Deshlahra   culations and surface researches. There is  reported the optimised condition for the   PA 40, RE-610, X100, X301, X405, ANP30,  ExxonMobil   Hydrocarbon Solvents
       and C. Sykes (Tufts University, USA),  possibility of moving from model to rea-  title reaction. A macro-kinetic equation   OPS25, ET120, ET165 and many others
       with funding from US NSF, have found  lity. (Angew. Chem. Intl. Ed., 2024; DOI:  is also reported. The overall reaction effi-   Also available Emulsifier for:  Johnson Controls/Tyco     Chemguard (High Performance Fluorosurfactants)
       Cu as inexpensive alternative to gold for  10.1002/anie.202419661).  ciency of the title reactor was increased   Pigment Emulsion, Binder Manufacturing,                    Please contact:
       the silica-supported catalyst. Near 100%                           by 87.5% in comparison with stirred tank           Synthetic Adhesive Mfr.              Megachem Specialty Chemicals (I) Pvt. Ltd.
       selectivity for low-oxygen pressure VA  Boosting electrocatalytic   reaction (STR). The reaction was com-              Contact Manufacturer:                   (Formerly Known as MGI Chemicals Pvt. Ltd.)
       synthesis is reported.  The Cu-based  alcohol oxidation            pleted in 30 min. compared to 4 hr. in        fibrol NoN-ioNics Pvt. ltd.                      Group Company of Megachem Singapore
                                                                                                                                (AN ISO 9001:2015 Co.)
       catalyst,  in  place  of Au,  is  promising.                       STR.  (Chem. Eng. Processing-Process        Office:  B-7/8, Chandra Darshan, P.K. Road, Panch Rasta Jn.,  Office No. 702 & 703, Fairmount, Sector 17, Sanpada, Navi Mumbai - 400705
                                                                                                                         Mulund (W), Mumbai 400 080.
       (Chem. Eng. Prog., 2024, November).  Y. Chen  et al have mentioned that   Intensification, 2024,  205 No. 110020;       Cell:  8169945857 / 9930360291         Tel: +91-22-40260957/58 Email: info@in.megachem.com
                                         aminoxyl  radicals  electrocatalysis  DOI: 10.1016/j.cep.2024.110020).       Email:  info@fibrol.com l Web.: www.fibrol.com  Australia | China | India | Indonesia | Malaysia | Philipines | Singapore | Thailand | UAE | UK | Vietnam
       Homogeneous Mn-catalysed          presents a sustainable  way of oxidis-
       hydroamination of alkenes via     ing alcohols into high-value products.   CO-tolerant heterogeneous Ru                                AVAILABLE                                            Dealers in:
       the reductive coupling with       These authors have synthesised    catalysts for efficient formic                                                                                 • Calcium Chloride Fused/Prills 94-97%/Powder
       nitroarenes                       methylimidazole-functionalised   acid dehydrogenation                                   SODIUM SULPHITE                                          • Hydrogen Peroxide 50%
                                         4-acetylamino-2,2,6,6-tetrameth-                                                                                                                 • Caustic Soda Flakes  •  Chloroform
       A. Torres-Calis et al have reported an   ylpiperidine-N-oxyl derivative  with a  G. Xue et al worked on the development            MIN 98% PURITY                                  • Methylene Chloride  •  Maltodextrin
       efficient  and  operationally  simple  proto   strongly electron-withdrawing imid-  of improved and less costly catalysts for                                                      • Magnesium Chloride Hexahydrate
                                                                                                                                                                                              Contact: Mahendra Dye Chem
       col for  the title  reaction with homo-  azole  group. This  was  combined  with  the title reaction. The theoretical calcula-         PLEASE CONTACT                               G/F No 24, Girls School St, Kumarapark West, Sheshadripuram,
       geneous  catalyst.  Up  to  95%  yield  is   bioinspired Ni-supported carbonaceous  tions suggest that Ru nanoparticles sup-       FOR YOUR REQUIREMENT                               Bangalore - 560 020. w Email: mdcjain@gmail.com
       reported. This is a  novel  strategy  and   octopus tentacles for effective electroo-  ported on nitrogen-doped carbon should                                                      Mob: 6361387818 / 6361768754 w Ph: 080-2287 2066 / 2287 5844
       merits further attention.         xidation of alcohols. High current den-  be useful. Carbon nitride was used as                                                                   used, surPlus/ uNused chemical equiPmeNt
                                         sity of 200 mA per sq.cm. was deployed  template and phenanthroline as ligand.                                                                   l  UTILITIES (Boilers /    l  REACTORS /    l  PUMPS
                                                                                                                                                                                            Thermopacs,
                                                                                                                                                                                                      HYDROGENATORS
       Two-dimensional catalysts         and selectivity was 99%, with turnover  The catalyst has good thermal stability        MFD BY:-                                                    Chilling Plants)  l  BLENDERS   l  LABORATORY
                                                                                                                                                                                                                EqUIPMENT
                                                                                                                                                                                          l  CENTRIFUGES
                                                                                                                                                                                                    l  MATERIAL HANDLING     (G.C, HPLC, Glass
                                                            -1
       (TDCs)                            frequency of 26,490 hr . The  catalyst  and a high turnover frequency (TOF >   GULSHAN CHEMICALS PRIVATE LIMITED                                 l  COLUMNS /      EqUIPMENT      Assemblies etc)
                                                                                                                                                                                            CONDENSORS
                                                                                                                                                                                                      (Fork Lifts, Screw-
                                         is water-soluble and separation can be  1,300 h ) and this is one order of magni-                                                                l  DRYERS     belt-slat Conveyors,     SURPLUSES: Valves,
                                                                                                                                                                                                              l  INVENTORY
                                                                                -1
                                                                                                                                                                                                      Hoists, Storage
       M. Zhang et al have mentioned that TD  done  easily.  Scale-up  was  done  in  a  tude higher than that of commercial     703-705, DLF PLACE, SAKET, NEW DELHI - 110017            l  FLAKERS    Pallets etc)    Cables, Pipes &
                                                                                                                                                                                                                fittings,
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                                                                                                                                                                                                                PRV Stations etc)
                                                                                                                                                                                                    l  STORAGE
       materials have been utilised broadly  continuous  flow  electrolyser.  (A.I.Ch.  Ru5/C catalyst. (Angew. Chem. Intl. Ed.,      Tel: 011 - 41041504, Mob No: 9999689337             l  ANF / ANFD  for buying or selling the above, Please contact:-
                                                                                                                                                                                                      VESSELS
       in catalytic reactions due to their fully   E. Jl., 2024; DOI: 10.1002/aic.18662).  2024; DOI: 10.1002/anie.202416530).  Email : contact@gulshanchemicals.com, sales@gulshanchemicals.com  Allied Equipment Corporation
                                                                                                                                       Website: www.gulshanchemicals.com                      Mobile / Whatsapp: 9821359802
                                                                                                                                                                                              Email: kunalmundle@hotmail.com
                                                                                                                     13/27
       172                                                                   Chemical Weekly  January 28, 2025
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